Geopolymer concrete: Properties, durability and applications: Review

Authors

DOI:

https://doi.org/10.5937/ror2201063J

Keywords:

geopolymer, concrete, fly ash, durability, OPC

Abstract

Concrete is one of the most reliable, durable, and desired construction materials. It became the second most used material after water in the world. Many studies and investigations reported that the amount of CO2 released into the atmosphere is nearly 1 ton in the production of 1 ton of cement, which contributes to 5-7 % of total CO2 emissions worldwide. Geopolymer concrete (GPC) is a new development in the world of concrete, which does not need to use cement. The most used materials in geopolymer are by-products such as fly ash, ground granulated blast furnace slag, silica fume, etc. Industrial waste materials are a great problem for human health, environment, and scarcity of land, therefore, reusing them in GPC manufacturing can be seen as a great advantage. Fortunately, most of the recent research concludes that most by-products exhibit similar or better durability, mechanical and physical properties when compared to ordinary concrete. Therefore, GPC became a good sustainable engineering material with many advantages over conventional concrete, such as high early strength, excellent resistance to chemical attacks and steel reinforcement corrosion, elimination of water curing, low cost, etc. This paper reviews the process of geopolymer concrete, constituents, types, properties, durability, and particular applications.

References

Astutiningsih, S., Nurjaya, D.M., Ashadi, H.W., Swastika, N., Durability of Geopolymer Concretes upon Seawater Exposure, Adv. Sci. Technol., 69, 2010, 92-96,

https://doi.org/10.4028/www.scientific.net/AST.69.92

Aleem, M.I.A., Arumairaj, P.D., Geopolymer Concrete - A review, International Journal of Engineering Sciences & Emerging Technologies, 1, 2012, 118-122,

https://doi.org/10.7323/ijeset/v1_i2_14

Astutiningsih, S., Nurjaya, D.M., Ashadi, H.W., Swastika, N., Durability of Geopolymer Concretes upon Seawater Exposure, Adv. Sci. Technol., 69, 2010, 92-96,

https://doi.org/10.4028/www.scientific.net/AST.69.92

Aleem, M.I.A., Arumairaj, P.D., Geopolymer Concrete - A review, International Journal of Engineering Sciences & Emerging Technologies, 1, 2012, 118-122,

https://doi.org/10.7323/ijeset/v1_i2_14

Albitar, M., Mohamed Ali, M.S., Visintin, P., Drechsler, M., Durability evaluation of geopolymer and conventional concretes, Constr. Build. Mater., 136, 2017, 374-385,

https://doi.org/10.1016/j.conbuildmat.2017.01.056

Al-Mashhadani, M. M., Canpolat, O., Aygörmez, Y., Uysal, M., Erdem, S., Mechanical and microstructural characterization of fiber reinforced fly ash based geopolymer composites, Construction and building materials, 167, 2018, 505-513,

https://doi.org/10.1016/j.conbuildmat.2018.02.061

Assi, L. N., Deaver, E. E., Ziehl, P., Effect of source and particle size distribution on the mechanical and microstructural properties of fly Ash-Based geopolymer concrete, Construction and Building Materials, 167, 2018, 372-380,

https://doi.org/10.1016/j.conbuildmat.2018.01.193

Aly, A. M., El-Feky, M. S., Kohail, M., Nasr, E. S. A., Performance of geopolymer concrete containing recycled rubber, Construction and Building Materials, 207, 2019, 136-144, Aygörmez, Y., Canpolat, O., Al-mashhadani, M.M., Assessment of geopolymer composites durability at one year age, J. Build. Eng., 32, 2020, 101453,

https://doi.org/10.1016/j.conbuildmat.2019.02.121

Bakharev, T., Resistance of geopolymer materials to acid attack, Cem. Concr. Res., 35, 2005, 658-670,

https://doi.org/10.1016/j.cemconres.2004.06.005

Bakri, A.M.M. Al, Kamarudin, H., Bnhussain, M., Nizar, I.K., Rafiza, A.R., Zarina, Y., The Processing, Characterization, And Properties of Fly Ash Based Geopolymer Concrete, Reviews on Advanced Materials Science, 30(1), 2012, 90-97,

Bhikshma, V., Koti Reddy, M., Srinivas Rao, T., An Experimental Investigation on Properties of Geopolymer Concrete (No Cement Concrete), Asian Journal of Civil Engineering (Building and Housing), 13(6), 2012, 841-853,

Burduhos Nergis, D.D., Abdullah, M.M.A.B., Vizureanu, P., Tahir, M.F.M., Geopolymers and Their Uses : Review, IOP Conf. Series: Materials Science and Engineering, 374(1), 2018, 012019,

https://doi.org/10.1088/1757-899X/374/1/012019

Bagheri, A., Nazari, A., Hajimohammadi, A., Sanjayan, J. G., Rajeev, P., Nikzad, M., Mendis, P., Microstructural study of environmentally friendly boroaluminosilicate geopolymers, Journal of Cleaner Production, 189, 2018, 805-812,

https://doi.org/10.1016/j.jclepro.2018.04.034

Chowdhury, S., Mohapatra, S., Gaur, A., Dwivedi, G., Soni, A., Study of various properties of geopolymer concrete - A review, Materials Today: Proceedings, 46, 2021, 5687-5695,

https://doi.org/10.1016/j.matpr.2020.09.835

Davidovits, J., Properties of geopolymer cements, In Kiev (Ed.), First international conference on alkaline cements and concretes, Kiev, Ukraine: Kiev State Technical University, 1, 1994, 131-149,

Davidovits, J., Geopolymer Cement A Review, Geopolymer Sci. Tech, 2013, 1-11,

https://doi.org/10.1520/STP156620120106

El-Hassan, H., Ismail, N. Effect of Process Parameters on The Performance of Fly Ash / GGBS Blended Geopolymer Composites. J. Sustain. Cem. Mater., 2017, 1-19,

Farhana, Z.F., Kamarudin, H., Rahmat, A., Al Bakri, A.M.M., The relationship between water absorption and porosity for geopolymer paste. Mater. Sci., 803, 2015, 166-172,

https://doi.org/10.4028/www.scientific.net/MSF.803.166

Granizo, M. L., Blanco-Varela, M. T., Martínez-Ramírez, S., Alkali activation of metakaolins: parameters affecting mechanical, structural and microstructural properties, Journal of Materials Science, 42(9), 2007, 2934-2943,

https://doi.org/10.1007/s10853-006-0565-y

Guo, L., Wu, Y., Xu, F., Song, X., Ye, J., Duan, P., Zhang, Z., Sulfate resistance of hybrid fiber reinforced metakaolin geopolymer composites, Composites Part B: Engineering, 183, 2020, 107689,

https://doi.org/10.1016/j.compositesb.2019.107689

Gupta, R., Bhardwaj, P., Mishra, D., Prasad, M., Amritphale, S. S., Formulation of mechanochemically evolved fly ash based hybrid inorganic-organic geopolymers with multilevel characterization, Journal of Inorganic and Organometallic Polymers and Materials, 27(2), 2017, 385-398,

https://doi.org/10.1007/s10904-016-0461-0

Gupta, N., Gupta, A., Saxena, K. K., Shukla, A., Goyal, S. K., Mechanical and durability properties of geopolymer concrete composite at varying superplasticizer dosage, Materials Today: Proceedings, 44, 2021, 12-16,

https://doi.org/10.1016/j.matpr.2020.05.646

Hardjito, D., Wallah, S.E., Sumajouw, D.M.J., Rangan, B.V., On the Development of Fly Ash-Based Geopolymer Concrete, ACI Materials Journal, 101(6), 2004, 467-472,

https://doi.org/10.14359/13485

Heah, C. Y., Kamarudin, H., Al Bakri, A. M., Binhussain, M., Luqman, M., Nizar, I. K., ... & Liew, Y. M., Effect of curing profile on kaolin-based geopolymers, Physics Procedia, 22, 2011, 305-311,

https://doi.org/10.1016/j.phpro.2011.11.048

He, J., Jie, Y., Zhang, J., Yu, Y., Zhang, G., Synthesis and characterization of red mud and rice husk ash-based geopolymer composites, Cement and Concrete Composites, 37, 2013, 108-118,‏

https://doi.org/10.1016/j.cemconcomp.2012.11.010

Huseien, G.F., Mirza, J., Ismail, M., Hussin, M.W., Arrifin, M.A.M., Hussein, A.A., The Effect of Sodium Hydroxide Molarity and Other Parameters on Water Absorption of Geopolymer Mortars, Indian Journal of Science and Technology, 9(48), 2016, 1-7,

https://doi.org/10.17485/ijst/2016/v9i48/109629

Hajimohammadi, A., van Deventer, J.S.J., Solid reactant-based geopolymers from rice hull ash and sodium aluminate, Waste and Biomass Valorization, 8(6), 2017, 2131-2140,

https://doi.org/10.1007/s12649-016-9735-6

Hariz, Z., Mohd, A., Al, M., Kamarudin, H., Nurliyana, A., Ridho, B., Review on Various Types of Geopolymer Materials With The Environmental Impact Assessment, MATEC Web of Conferences, 97, 2017, 01021,

https://doi.org/10.1051/matecconf/20179701021

Hu, W., Nie, Q., Huang, B., Shu, X., He, Q., Mechanical and microstructural characterization of geopolymers derived from red mud and fly ashes, Journal of Cleaner Production, 186, 2018, 799-806,

https://doi.org/10.1016/j.jclepro.2018.03.086

Hassan, A., Arif, M., Shariq, M. Use of geopolymer concrete for a cleaner and sustainable environment - A review of mechanical properties and microstructure, Journal of cleaner production, 223, 2019, 704-728,

https://doi.org/10.1016/j.jclepro.2019.03.051

Joseph, B., Mathew, G., Influence of aggregate content on the behaviour of fly ash based geopolymer concrete, Scientia Iranica, 19(5), 2012, 1188-1194,

https://doi.org/10.1016/j.scient.2012.07.006

Jamkar, S. S., Ghugal, Y. M., Patankar, S. V., Effect of fly ash fineness on workability and compressive strength of geopolymer concrete, The Indian Concrete Journal, 87(4), 2013, 57-61,

Jawahar, J.G., Mounika, G. Strength Properties of Fly Ash and GGBS Based Geopolymer Concrete, Asian Journal of Civil Engineering, 17(1), 2016, 127-135,

Kusbiantoro, A., Ibrahim, M. S., Muthusamy, K., Alias, A., Development of sucrose and citric acid as the natural based admixture for fly ash based geopolymer, Procedia Environmental Sciences, 17, 2013, 596-602,

https://doi.org/10.1016/j.proenv.2013.02.075

Kumar, S.G., Aleem, M.I.A., Dinesh, S., Application of Geopolymer Concrete, International Research Journal of Engineering and Technology (IRJET), 2(9), 2015, 96-99,

Kaya, K., Soyer-Uzun, S., Evolution of structural characteristics and compressive strength in red mud-metakaolin based geopolymer systems, Ceramics International, 42(6), 2016, 7406-7413,

https://doi.org/10.1016/j.ceramint.2016.01.144

Kashani, A., Ngo, T. D., Mendis, P., The effects of precursors on rheology and self-compactness of geopolymer concrete, Magazine of Concrete Research, 71(11), 2019, 557-566,

https://doi.org/10.1680/jmacr.17.00495

Lavanya, G., Jegan, J., Durability Study on High Calcium Fly Ash Based Geopolymer Concrete, Advances in Materials Science and Engineering, 2015, 731056,

https://doi.org/10.1155/2015/731056

Law, D.W., Arham, A., Thomas, A., Patnaikuni, I., Wardhono, A., Long Term Durability Properties of Class F Fly Ash Geopolymer Concrete. Materials and Structures, 48, 2015, 721-731,

https://doi.org/10.1617/s11527-014-0268-9

Mucsi, G., Rácz, Á., Molnár, Z., Szabó, R., Gombkötő, I., Debreczeni, Á. Synergetic use of lignite fly ash and metallurgical converter slag in geopolymer concrete. Mining Science. 2014, 21, 43-55,

Muthadhi, A., Vanjinathan, J., Durai, D., Experimental investigations on geo polymer concrete based on class C fly ash, Indian journal of Science and Technology, 9(5), 2016, 1-5,

https://doi.org/10.17485/ijst/2016/v9i5/87270

Mehta, A., Siddique, R. An overview of geopolymers derived from industrial by-products, Construction and Building Materials, 127, 2016, 183-198,

https://doi.org/10.1016/j.conbuildmat.2016.09.136

Mesgari, S., Akbarnezhad, A., Xiao, J. Z., Recycled geopolymer aggregates as coarse aggregates for Portland cement concrete and geopolymer concrete: Effects on mechanical properties, Construction and Building Materials, 236, 2020, 117571,

https://doi.org/10.1016/j.conbuildmat.2019.117571

Masoule, M. S. T., Bahrami, N., Karimzadeh, M., Mohasanati, B., Shoaei, P., Ameri, F., & Ozbakkaloglu, T., Lightweight geopolymer concrete: A critical review on the feasibility, mixture design, durability properties and microstructure, Ceramics International, 2022,

Nath, P., Sarker, P. K., Effect of GGBFS on setting, workability and early strength properties of fly ash geopolymer concrete cured in ambient condition, Construction and Building materials, 66, 2014, 163-171,

https://doi.org/10.1016/j.conbuildmat.2014.05.080

Nuaklong, P., Sata, V., Chindaprasirt, P., Influence of recycled aggregate on fly ash geopolymer concrete properties, Journal of Cleaner Production, 112, 2016, 2300-2307,

https://doi.org/10.1016/j.jclepro.2015.10.109

Pasupathy, K., Berndt, M., Sanjayan, J., Rajeev, P., Cheema, D.S., Durability Performance of Precast Fly Ash-Based Geopolymer Concrete under Atmospheric Exposure Conditions, J. Mater. Civ. Eng, 30(3), 2018, 04018007,

https://doi.org/10.1061/(ASCE)MT.1943-5533.0002165

Parathi, S., Nagarajan, P., Pallikkara, S. A., Ecofriendly geopolymer concrete: a comprehensive review, Clean Technologies and Environmental Policy, 23(6), 2021, 1701-1713,

https://doi.org/10.1007/s10098-021-02085-0

Rovnaník, P., Effect of Curing Temperature on the Development of Hard Structure of Metakaolin-Based Geopolymer, Constr. Build. Mater., 24(7), 2010, 1176-1183,

https://doi.org/10.1016/j.conbuildmat.2009.12.023

Raijiwala, D.B., Patil.H.S., Geopolymer Concrete: A Concrete of Next Decade, Journal of Engineering Research and Studies, 2(1), 2011, 19-25,

Rattanasak, U., Pankhet, K., Chindaprasirt, P., Effect of chemical admixtures on properties of high-calcium fly ash geopolymer, International Journal of Minerals, Metallurgy, and Materials, 18(3), 2011, 364-369,‏

https://doi.org/10.1007/s12613-011-0448-3

Rai, S., Wasewar, K., Mukhopadhyay, J., Yoo, C. K., Uslu, H., Neutralization and utilization of red mud for its better waste management, Arch. Environ. Sci, 6, 2012, 13-33,

Sathia, R., Ganesh Babu, K., Santhanam, M., Durability study of low calcium fly ash geopolymer concrete, The 3rd ACF international conference, 2008, -ACF/VCA 2008.1153-1159,

Shaikh, F.U.A., Effects of Alkali Solutions on Corrosion Durability of Geopolymer Concrete, Advances in Concrete Construction, 2(2), 2014, 109-123,

https://doi.org/10.12989/acc.2014.2.2.109

Sarker, P.K., Kelly, S., Yao, Z., Effect of Fire Exposure on Cracking, Spalling and Residual Strength of Fly Ash Geopolymer Concrete, Mater. Des., 63, 2014, 584-592,

https://doi.org/10.1016/j.matdes.2014.06.059

Singh, B., Ishwarya, G., Gupta, M., Bhattacharyya, S. K., Geopolymer concrete: A review of some recent developments, Construction and building materials, 85, 2015, 78-90,

https://doi.org/10.1016/j.conbuildmat.2015.03.036

Singh, N.B., Saxena, S.K., Kumar, M., Rai, S. Geopolymer Cement : Synthesis, Characterization, Properties and Applications, Mater. Today Proc., 15, 2019, 364-370,

https://doi.org/10.1016/j.matpr.2019.04.095

Safari, Z., Kurda, R., Al-Hadad, B., Mahmood, F., Tapan, M., Mechanical Characteristics of Pumice-Based Geopolymer Paste, Resour. Conserv. Recycl., 162, 2020, 105055,

https://doi.org/10.1016/j.resconrec.2020.105055

Thokchom, S., Ghosh, P., Ghosh, S., Effect of water absorption, porosity and sorptivity on durability of geopolymer mortars, J. Eng. Appl. Sci., 4, 2009, 28-32.

Vijai, K., Kumutha, R., Vishnuram, B.G. Effect of Types of Curing on Strength of Geopolymer Concrete, International Journal of the Physical Sciences, 5(9), 2010, 1419-1423,

Wardhono, A., Law, D. W., Sutikno, Dani, H., The effect of slag addition on strength development of Class C fly ash geopolymer concrete at normal temperature, In AIP Conference Proceedings, 1887(1), 2017, 020030. AIP Publishing LLC,

https://doi.org/10.1063/1.5003513

Wu, Y., Lu, B., Yi, Z., Du, F., Zhang, Y. The Properties and Latest Application of Geopolymers the Properties and Latest Application of Geopolymers, IOP Conf. Series: Materials Science and Engineering, 472(1), 2019, 012029,

https://doi.org/10.1088/1757-899X/472/1/012029

Wang, A., Zheng, Y., Zhang, Z., Liu, K., Li, Y., Shi, L., Sun, D. The Durability of Alkali-Activated Materials in Comparison with Ordinary Portland Cements and Concretes: A Review, Engineering, 6(6), 2020, 695-706,

https://doi.org/10.1016/j.eng.2019.08.019

Zhang, H. Y., Kodur, V., Wu, B., Cao, L., Wang, F., Thermal Behavior and Mechanical Properties of Geopolymer Mortar after Exposure to Elevated Temperatures, Construction and Building Materials, 109, 2016, 17-24,

https://doi.org/10.1016/j.conbuildmat.2016.01.043

Zain, H., Abdullah, M. M. A. B., Hussin, K., Ariffin, N., Bayuaji, R., Review on various types of geopolymer materials with the environmental impact assessment, In MATEC Web of Conferences, EDP Sciences, 97, 2017, 01021.

https://doi.org/10.1051/matecconf/20179701021

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15-12-2022

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