Functionalized geopolymers: A review

Authors

  • Nóra Halyag University of Miskolc, Institute of Raw Material Preparation and Environmental Processing, Miskolc, Hungary Author
  • Gábor Mucsi University of Miskolc, Institute of Raw Material Preparation and Environmental Processing, Miskolc, Hungary Author https://orcid.org/0000-0003-1031-2801

DOI:

https://doi.org/10.5937/ror1801001H

Keywords:

Geopolymer, Alkali activated aluminosilicate, Geopolymer foam, Surface functionalization

Abstract

The geopolymer technology provides an alternative good solution for the utilization of industrial waste and the preservation of primary minerals to produce an economically valuable product that can be used for several purposes. This review summarizes the preparation, the structure modifications and functionalization of geopolymers for adsorbing purposes. The mechanical performances of the geopolymers (compressive strength, flexural strength, durability such as resistance to sulfate, acid, thermal effect) are the primary concerns that depend on the chemical composition.

References

Alshaaer M., El-Eswed B., Yousef R. I., Khalili F., Rahier H., Development of functional geopolymers for water purification, and construction purposes, Journal of Saudi Chemical Society, 20, 2016, 585-592,

https://doi.org/10.1016/j.jscs.2012.09.012

Al-Zboon K., Al-Harahsheh M. S., Hani F. B., Fly ash-based geopolymer for Pb removal from aqueous solution, Journal of Hazardous Materials, 188 (1-3), 2011, 414-421,

https://doi.org/10.1016/j.jhazmat.2011.01.133

Autef E., Joussein G., Gasgnier S., Rossignol S., Role of the silica source on the geopolymerization rate, Journal of Non-Crystalline Solids, 358 (21), 2012, 2886-2893,

https://doi.org/10.1016/j.jnoncrysol.2012.07.015

Barbsa V. F. F., MacKenzie K. J. D., Thaumaturgo C. D., Synthesis and Characterization of sodium polysialate inorganic polymer based on alumina and silica, Proceedings - '99 Geopolymer International Conference, 2nd ed., Saint-Quentin, France, June 30 - July 2, 1999, 65-78, Editors: Davidovits J. and Orlinski J., Publisher: Geopolymer Institute, Saint-Quentin, France, ISBN: 2902933142 9782902933143

Cilla M. S., Morelli M. R., Colombo, P., Open cell geopolymer foams by a novel saponification/peroxide/gelcasting combined route, Journal of the European Ceramic Society, 34, 2014, 3133-3137,

https://doi.org/10.1016/j.jeurceramsoc.2014.04.001

Davidovits J., Geopolymers and geopolymeric new materials, Journal of thermal analysis, 35 (2), 1989, 429-441,

https://doi.org/10.1007/BF01904446

Duan P., Yan C., Zhou W., Ren D., Development of fly ash and iron ore tailing based porous geopolymer for removal of Cu (II) from wastewater, Ceramics International, 42, 2016, 13507-13518,

https://doi.org/10.1016/j.ceramint.2016.05.143

Hadi P., Kubicki C. N. J. D., Mueller K., Fagan J. W., Luo Z., Weng L., McKay G., Sustainable development of a surface-functionalized mesoporous aluminosilicate with ultra-high ion exchange efficiency, Inorganic Chemistry Frontiers, 3 (4), 2016, 502-513,

https://doi.org/10.1039/C5QI00182J

Javadian H., Ghorbani F., Tayebi H., Hosseini S. F., Study of the adsorption of Cd (II) from aqueous solution using zeolite-based geopolymer, synthesized from coal fly ash; kinetic, isotherm and thermodynamic studies, Arabian Journal of Chemistry, 8 (6), 2015, 837-849,

https://doi.org/10.1016/j.arabjc.2013.02.018

Kumar S., Mucsi G., Kristály F., Pekker P., Mechanical activation of fly ash and its influence on micro and nano-structural behaviour of resulting geopolymers, Advanced Powder Technology, 28 (3), 2017, 805-813,

https://doi.org/10.1016/j.apt.2016.11.027

Lee N. K., Khalid H. R., Lee H. K., Adsorption characteristics of cesium onto mesoporous geopolymers containing nano-crystalline zeolites, Microporous and Mesoporous Materials, 242, 2017, 238-244,

https://doi.org/10.1016/j.micromeso.2017.01.030

Li Z., Chen R., Zhang L.Y., Utilization of chitosan biopolymer to enhance fly ash-based geopolymer, Journal of Materials Science, 48 (22), 2013, 7986-7993,

https://doi.org/10.1007/s10853-013-7610-4

López F. J., Sugita S., Tagaya M., Kobayashi T., Geopolymers Using Rice Husk Silica and Metakaolin Derivatives; Preparation and Their Characteristics, Journal of Materials Science and Chemical Engineering, 2 (5), 2014, 35-43,

https://doi.org/10.4236/msce.2014.25006

Mucsi G., Kumar S., Csőke B., Kumar R., Molnár Z., Rácz Á., Mádai F., Debreczeni Á., Control of geopolymer properties by grinding of land filled fly ash, International Journal of Mineral Processing, 143, 2015, 50-58,

https://doi.org/10.1016/j.minpro.2015.08.010

Palmero P., Formia A., Antonacib P., Brinic S., Tulliani J. M., Geopolymer technology for application-oriented dense and lightened materials. Elaboration and characterization, Ceramics International, 41 (10, Part A), 2015, 12967-12979,

https://doi.org/10.1016/j.ceramint.2015.06.140

Pizarro J., Castillo X., Jara S., Ortiz C., Navarro P., Cid H., Rioseco H., Barros D., Belzile N., Adsorption of Cu2+ on coal fly ash modified with functionalized mesoporous silica, Fuel, 156, 2015, 96-10,

https://doi.org/10.1016/j.fuel.2015.04.030

Ricciotti L., Roviello G., Tarallo O., Borbone F., Ferone C., Colangelo F., Synthesis and characterizations of melamine-based epoxy resins, International Journal of Molecular Sciences, 14 (9), 2013, 18200-18214,

https://doi.org/10.3390/ijms140918200

Rickard W. D. A., Vickers L., Riessen A. V., Performance of fibre reinforced, low density metakaolin geopolymers under simulated fire conditions, Applied Clay Science, 73, 2013, 71-77,

https://doi.org/10.1016/j.clay.2012.10.006

Svingala F., Varela B., Alkali Activated Aerogels, Mechanical Properties and Performance of Engineering Ceramics and Composites IV, 30 (2), 2009, 325-333,

https://doi.org/10.1002/9780470584262.ch30

Szabó R., Gombkötő I., Svéda M., Mucsi G., Effect of grinding fineness of fly ash on the properties of geopolymer foam, Archives of Metallurgy and Materials, 62 (2B), 2017, 1257-1261,

https://doi.org/10.1515/amm-2017-0188

Temuujin J., Minjigmaa A., Bayarzul U., Kim D. S., Lee S-Ho., Ruescher C. H., MacKenzie K. J. D., Properties of geopolymer binders prepared from milled pond ash, Materiales De Construccion, 67 (328), 2017, 1-11,

https://doi.org/10.3989/mc.2017.07716

Xu H., Van Deventer J. S. J., The geopolymerisation of aluminosilicate minerals, International Journal of Mineral Processing 59 (3), 2000, 247-266,

https://doi.org/10.1016/S0301-7516(99)00074-5

Yang T., Yao X., Zhang Z. H., Geopolymer prepared with high-magnesium nickel slag: characterization of properties and microstructure, Construction and Building Materials, 59, 2014, 188-194,

https://doi.org/10.1016/j.conbuildmat.2014.01.038

Yousef R. I., El-Eswed B., Alshaaer M., Khalili F., Khoury H., The influence of using Jordanian natural zeolite on the adsorption, physical, and mechanical properties of geopolymers products, Journal of Hazardous Materials, 165 (1-3), 2009, 379-387,

https://doi.org/10.1016/j.jhazmat.2008.10.004

Yuanyuan G., Xuemin C., Chunli L., Zhili L., Facile fabrication of green geopolymer/alginate hybrid spheres for efficient removal of Cu(II) in water: Batch and column studies, Chemical Engineering Journal, 311, 2017, 126-134,

https://doi.org/10.1016/j.cej.2016.11.079

Yuanyuan G., Yuan Y., Kaituo W., Yan H., Xuemin C., Preparation of geopolymer-based inorganic membrane for removing Ni2+ from wastewater, Journal of Hazardous Materials, 299, 2015, 711-718,

https://doi.org/10.1016/j.jhazmat.2015.08.006

Zhang Z., Provis J. L., Reid A., Wang H., Geopolymer foam concrete: An emerging material for sustainable construction, Construction and Building Materials, 56, 2014, 113-127,

https://doi.org/10.1016/j.conbuildmat.2014.01.081

Zhang Z., Yao X., Zhu H., Hua S., Chen Y., Preparation and mechanical properties of polypropylene fiber reinforced calcined kaolin-fly ash based geopolymer, Journal of Central South University of Technology, 16 (1), 2009, 49-52,

https://doi.org/10.1007/s11771-009-0008-4

Zhuang X. Y., Chen L., Komarneni S., Zhou C. H., Tong D. S., Yang H. M., Yu W. H., Wang H., Fly ash-based geopolymer: clean production, properties and applications, Journal of Cleaner Production, 125, 2016, 253-267.

https://doi.org/10.1016/j.jclepro.2016.03.019

Downloads

Published

15-12-2018

Issue

Section

Articles